Material Safety Data Sheet for Outdoor Additive
MATERIAL SAFETY DATA SHEET Revision date: 5/12/2006 BUSAN 11-M7 24 Hour Emergency Phone: (901) 767-2722 1. OSHA HAZARD CLASSIFICATIONS
Irritating to eyes.
2. HAZARDOUS COMPONENTS
B. Labs reports the component(s) listed above as known OSHA hazardous material(s) contained in this product. B. Labs considers any product/component having an established exposure limit (a TLV/TWA) or containing a known carcinogen (present over 0.1%) as being an OSHA hazardous material. As listed in Section 5 Busan 11-M7 does not contain a known carcinogen but it does have an established TWA of 0.5 mg/m3. Even though this product contains a known OSHA hazardous material this should not pose a problem because people handling this product, as described, will not be exposed to a TWA of > 0.5 mg.m3. 3. FIRST AID INFORMATION
Eye Exposure: Flush immediately with copious amounts of tap water or normal saline (minimum of 15
minutes). Take exposed individual to a health care professional, preferably an ophthalmologist, for further evaluation.
Skin Exposure: Inhalation: Ingestion: 4. PRIMARY ROUTES OF EXPOSURE
1. Effects from Acute Exposure:Eye exposure: lightly hazardous in case of eye contact (irritant). Skin Exposure: Non-irritant for skin. Non-sensitizer for skin. Inhalation: Slightly hazardous in case of inhalation. Effects will depend on concentration and length of time of exposure. Ingestion: May be hazardous in case of ingestion. Effects will depend on concentration and length of time of exposure. 2. Effects from Chronic Exposure:The effects from chronic exposure to this product have not been evaluated. Chronic ingestion of some barium compounds may have an adverse effect on the cardiovascular system. May cause damage to the following organs: the reproductive system, cardiovascular system, upper respiratory tract, eyes. Boron compounds have been associated with reproductive effects in animal studies. 5. Toxicological Information
Acute Effects: Acute Oral (LD50) = 850 mg/kg Male rat
Acute Oral (LD50) = 530 mg/kg Female rat Acute Dermal (LD50) = >2000 mg/kg Rabbit Acute Inhalation (LC50) = >2.54 mg/l (4 hours) Rat Carcinogenic Potential: Not tested by B.Labs. Not shown as a carcinogen by OSHA, IARC, or NTP. Irritant/Sensitization Effects: Slightly hazardous in case of eye contact (irritant). Non-irritant for skin. Non-sensitizer for skin. Slightly hazardous in case of inhalation. Effects will depend on concentration and length of time of exposure. 6. Environmental Toxicological Information
LC50 = 20.3 mg/l 48 hours Daphnia magnaLC50 = >151 mg/l 96 hours Bluegill sunfish LC50 = >62 mg/l 96 hours Rainbow trout 7. Physical and Chemical Properties
8. Fire and Explosion Information
Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
9. Reactivity Information
10. Handling Precautions
Eye-wash fountains in the work place are recommended. Nuisance dust masks required when the TLV may
be exceeded. Rubber gloves, protective eyewear and body protective clothing and shoes are recommended.
11. Satisfactory Materials of Construction
This product is a corrosion inhibitor and is commonly used in contact with all reasonable industrial surfaces.
If questions arise concerning the compatibility of this product with any container, please contact B.Labs, Inc.,
at the phone number on the first page of this MSDS.
12. SPILL AND LEAK RESPONSE GUIDELINES
Important: Before responding to a spill or leak of this product, review each section of this MSDS. Follow the recommendations given in the Handling Precautions sections. Check the Fire and Explosion Data section to determine if the use of non-sparking tools is merited. Insure that spilled or leaked product does not come into contact with materials listed as incompatible. If irritating fumes are present, consider evacuation of enclosed areas. Emergency Response Assistance: Emergency technical assistance is available at any time from B.Labs, Inc., by calling (901) 767-2722. Initially minimize area effected by the spill or leak. Block any potential routes to water systems (e.g., sewers, streams, lakes, etc.). Based on the product's toxicological and chemical properties, and on the size and location of the spill or leak, assess the impact on contaminated environments (e.g. water systems, ground, air equipment, etc.). There are no methods available to completely eliminate any toxicity this product may have on aquatic environments. Minimize adverse effects on these environments. B.Labs, Inc. can be contacted for technical assistance. Determine if federal, state, and/or local release notification is required (see Regulatory Classifications section of this MSDS). Recover as much of the pure product as possible into appropriate containers. Later, determine if this recovered product can be used for its intended purpose. Address clean-up of contaminated environments. Spill or leak residuals may have to be collected and disposed of. Flushing residual material to an industrial sewer, if present at the site of a spill or leak incident, may be acceptable if authorized approval is obtained. If product and/or spill/leak residuals are flushed to an industrial sewer, insure that they do not come into contact with incompatible materials. Contact the person(s) responsible for the operation of your facility's industrial sewer system prior to intentionally flushing spills or leaks of this product to the industrial sewer. DISPOSAL GUIDELINESNote: Follow federal, state, and local regulations governing the disposal of waste materials. Neat Product: Contact your B. Labs representative or B.Labs, Inc., at (901) 278-0330. Contaminated Materials: Determine if waste containing this product can be handled by available industrial effluent system or other on-site waste management unit. If off-site management is required, contact a company experienced in industrial waste management. This product is not specifically listed in 40 CFR 261 as a Resource Conservation and Recovery Act (RCRA) hazardous waste. However, spill or leak residuals may meet the criteria of a characteristic hazardous waste under this Act. Check the characteristics of the material to be disposed of and/or the physical and reactivity data given in this MSDS for the neat product. Container Disposal: Empty containers, as defined by appropriate sections of the RCRA, are not RCRA hazardous wastes. However, insure proper management of any residuals remaining in container. 12. SPILL, LEAK, DISPOSAL PROCEDURES
Not Regulated.Not Regulated. Not Regulated. 13. Transportation and Shipping Information
DOT Shipping Information:IMO/IMDG Shipping Information: IATA Shipping Information: Unless otherwise stated, the shipping information provided above applies only to non-bulk containers of this product. Proper shipping name and general shipping information may vary depending on packaging and mode of shipment. All products shipped from Buckman locations have been properly packaged and labeled according to appropriate hazardous materials shipping regulations. If any alteration of packaging, product, or mode of transportation is further intended, different shipping information, including but not limited to proper shipping name, RQ designation, and labeling may apply. For further information pertaining to the shipping requirements for this product, contact Buckman's Transportation Department or DOT Coordinator. 14. REGULATORY INFORMATION
The following Regulations are known to apply to the use and disposal of this product. Additional Federal,
State and Local regulations may also be applicable.SARA (Superfund Admendments and Reauthorization Act) SARA 302 Extremely Hazardous Substances List... SARA 312 HAZARD CATEGORY... This product contains the following toxic chemical(s) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372 : Barium metaborate monohydrate CERCLA (Comprehensive Environmental Response, Compensation and Liability Act) Barium metaborate monohydrate ..... RQ = 1000 lbs. (453.6 kg) RCRA (Resource Converation and REcovery Act) Listed Hazardous Waste No components of this product are listed. CWA (Clean Water Act) Listed Substances FDA (Food and Drug Administration) This product is approved under the following FDA (21 CFR) sections : 176.180: Limitation: For use only as a preservative in coatings and sizings. TSCA (Toxic Substances Control Act) Applicability All components are listed on the TSCA Inventory. Registered pesticides are exempt from the requirements of TSCA. FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act) This product is a registered pesticide. EPA Reg. No. 1448-17 HMIS/MPCA Rating Health 2 Flammability 0 Reactivity 0 NFPA Ratings Health 2 Flammability 0 Reactivity 0 State Regulations Various State Right To Know Acts ... Non-proprietary hazardous chemicals are listed in Section 2 of this MSDS. Should you require further information on specific proprietary or inert ingredients please contact B. Labs' Regulatory Affairs Department. The information on this Material Safety Data Sheet reflects the latest information and data that we have on hazards, properties, and handling of this product under the recommended conditions of use. Any use of this product or method of application which is not described in the Data Sheet is the responsibility of the user. This Material Data Safety Sheet was prepared to comply with the OSHA Hazard Communication regulations. While some components are claimed Trade Secret under OSHA Hazard Communication regulations, all known OSHA hazards associated with the Trade Secret component(s), if contained in this product, are fully disclosed. B. Labs, Inc. warrants that this product conforms to its chemical description and is reasonably fit for the purpose referred to in the directions for use when used in accordance with the directions under normal conditions. Buyer assumes the risk of any use contrary to such directions. Seller makes no other warranty or representation of any kind, express or implied, concerning the product, including NO IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS OF THE GOODS FOR ANY OTHER PARTICULAR PURPOSE. No such warranties shall be implied by law and no agent of seller is authorized to alter this warranty in any way except in writing with a specific reference to this warranty. The exclusive remedy against seller shall be in a claim for damages not to exceed the purchase price of the product, without regard to whether such a claim is based upon breach of warranty or tort. Any controversy or claim arising out or relating to this contract, or breach thereof, shall be settle by arbitration in accordance with the commercial arbitration rules of the American Arbitration Association, and judgement upon the rendered by the Arbitrator(s) may be entered in any court having jurisdiction thereof. The opinions expressed herein are those of qualified experts within The Real Milk Paint Co. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and of these opinions and the conditions of use of this product are not within the control of The Real Milk Paint Co., it is the user’s obligation to determine the conditions of safe use of this product. |